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Hoping you are not using the position hierarchy.
One way to achieve this is by using AME and put in place a rule where approval is required from two supervisors (Exception:- when the PR is raised by a subordinate just below the top employee).
Another way to achive this is by excluding all the accounts from the job of approver 'A' in approval group (Not suggestible as maintaining jobs of employees in this scenario will be messy)