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There probably is no documented prcedure for this, so there are no guarantees this can/will work, but you might try this using Note 471566.1 : "Migrating Oracle E-Business Suite R12 from Linux 32-bit to Linux 64-bit" as a guideline.
Pre-req is that a 32-bit OS is installed first as per Note 761564.1 : "Oracle E-Business Suite Installation and Upgrade Notes Release 12 (12.1.1) for Linux x86"
For the database it's probably needed to use a tool like transportatble tablespaces/database or export/import to convert to 32-bit; check the docs to see what applies.