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There are a few Exadata specific parameters but you should feel right at home running 11.2 on Oracle Enterprise Linux. I bought the Kindle version of Expert Oracle Exadata and it was a good introduction. After I got access to the Cell Servers I was able to get the official Exadata documentation which is very thorough.
I also recommend "Expert Oracle Exadata": http://www.amazon.com/Expert-Oracle-Exadata-Apress/dp/1430233923