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Could you please share with me how you have customized the PO charge account since, i am looking this kind of requirement and we may need to do the same after we upgrade to R12.
Yes, all accounts should be built successfully before you will see the charge account in iProcurement.
You will need to setup the accrual account in the Purchasing Options - for the Operating Unit under the Control tab.
Purchasing Super User - Setup/Organizations/Purchasing Options - assuming that the dest type is expense.