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Have you tried setting the inventory organization in the financial options for that OU. You need to tie the OU and Inventory organization using the financial options form. Also, make sure that the item is purchasable, check the flags...
go to the org item of the item validation and look on the purchasing tab and see if it purchased and purchasable
Please navigate to financial options-->Supplier-purchasing tab-->inventory organization.please make sure your item is assigned to this organization