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Are you using positional Hierarchy for approval for your Purchasing? Please check what is the final approver's approval limit/Position and how much he can approve ... You will get "No approver found" when system failed to find a approver based on the amount/position in your PO.
Moreover after you define Positions etc.in HR, did you execute "Security list maintenance" concurrent request for your Business group? if not then execute the HR request and try to approve the PO.
check your approval groups and its respective assignments
I have the same problem, Did you get the solution?