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I think the only way without a customization is to use PO>>Communicate option in the tools and send the PO to requester/any mail id.
The out of the box functionality is limited and won't do exactly what you want.
But 1) You can set "PO: Secondary Email address" profile to send a copy to the email address in the profile.
2) You can write an alert that fires upon approval and formats and sends the PO to the requestor.
3) If you use iProcurement, the requestor can see the PO using the iProcurement homepage.
Other than that, you are looking at a customization.
Hope this helps,