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Have you checked these docs?
iProcurement Punchout Gives Error Indicating Unit Of Measure Is Not Configured For Purchasing (or Category is Invalid) [ID 438669.1]
Category XYZ Is Not Configured For Purchasing [ID 434969.1]
Punchout Fails For New Category In 12.0 With Category Xxxx Is Not Configured For Purchasing [ID 466369.1]
Punchout Is Failing After Upgrade To Rel 12: The Supplier Did Not Provide A Unit Of Measure. [ID 976231.1]
If none helps, you may need to log a SR.
We believe, after you check out (from punchout) process, UOM captured as EA, which is not defined as a UOM in your Inventory setup. Could you please check in the UOM setup (inventory) that EA and its conversion is defined. If not then configure and test it again.. Do let us know about the result.
Hope this helps.