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Could you please check the approval group. It not only depends on the amount of PO but also account range, Item range etc. It may be paas the rule for Document total but may be failing for other objects.
I hope this helps.
Check the following
Purchase Orders Remain in an Incomplete Status on Approval and the Action History Shows "No Action Taken" [ID 458222.1]
How to Diagnose No Approver Found (Document Status Remains Incomplete) and Build Default Approval List Failures in the Purchasing Approval Workflow [ID 295153.1]