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This is expected behavior. If you have made changes to approved PO, you need to reapprove them and then you will be able to cancel those.
Hope this helps,
I found that the PO archive tables were not in sync with the standard tables.
Since we have set the set to archive option on the purching documents at PO Approval, we need to reapprove the PO in order to update the archive table
So its necessary to create a revision and re approve the PO.
Thanks and Regards,