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Check the values for the attributes you mentioned purchasing_enabled_flag, stock_enabled_flag, outside_operation_flag at the org level. what are the values?
1) In Item Master , status is set to OBSOLETE and purchasable check box is unchecked . Item master organization was set in purchasing options .
2) Organization item , status is Active . stockable and Purchasable check boxes are checked and outside processing item unchecked . This is receiving org in Purchasing .
I think Purchasing is considering Master org status as it is validation org for purchasing .
we have changed item status to active and retried from WF, Issue resolved .