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Please post the details of the application release, database version and OS.
Can you find any errors in the Workflow log file?
All Purchase Orders or Requisitions Getting Stuck in Pre-Approved or In Process Status - Troubleshooting Checklist [ID 1104843.1]
Troubleshooting for Requisitions / Purchase Orders in Process or Pre-Approved Status [ID 225017.1]
Also, search MOS for (POAPPRV stuck) and go through the docs.
PS wrote:It is already referenced in (Troubleshooting for Requisitions / Purchase Orders in Process or Pre-Approved Status [ID 225017.1]).
Did you have a look at metalink note 134960.1.