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It is expected. From back-end you are passing the XML and using callout within B2B, you are changing it's content-type itself (converting it into excel). You may like to try below steps -
1. Pass XML to B2B from back-end through a JMS queue (use JMS internal listening channel in B2B to receive XML from JMS queue)
2. Set below custom JMS header from back-end while enquing the XML into JMS queue -
3. Turn off the validation in the agreement and redeploy it.
4. Run a test again