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If you could share more about your concerns, it might help us address or alleviate said concerns. Basically if your user's desktops are secure, then so are the passwords.
I have a serious security concern about saved passwords at user level
To delete them w/o user intervention you would need to delete their connections by removing the file(s) from their installs. To prevent the problem from happening again, you'd need to put down a new sqldeveloper.conf file in their bin directory that would keep them from saving passwords - example here