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You have to define an approval group and you can set authorization rules comprised of include/exclude and amount limit criteria for the Document Total, Account Range, and Location. For each position or job, you ultimately associate these approval groups with document types to implement your authorization rules.
You have to enable the encumbrance check box in the financial options and some setups in the AP check with your financial consultant.
If you enable the encumbrance and set the budget for the each department then it will reject the PO if it goes beyond your budget 100K.