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There are few tables where these informtions are being stored.
As per your requirement you can join these tables & get the exact details.
Define Standard Attachments
Navigation: Setup > Attachments
Category To Supplier
Description General Attachment
Date Type File
File GENERAL TERMS AND CONDITIONS.doc
PO: Terms and Conditions File Name_
For e-mailed of purchase orders this profile identifies the name of the optional terms and conditions file. This text file needs to be placed in one of the directories specified in the UTL_FILE parameter in the INIT.ORA file and the file path indicated by the profile PO: In File Path.
PO: Terms and Conditions filename
Create a PO and generate the standard report (Printed Purchase Order Report)... Let us know if it is working for you or not..
You can refer Doc ID: 554507.1 for details.