Can we derive the PO charge account from a DFF at the Item master level?

Summary:

The requirement is to see if we could derive a PO Charge account based on the Item Master record.

Content (please ensure you mask any confidential information):

What we intend to do is to create a DFF at the item level which stores the account segment. When we create a PO/ PR using this item, we want our charge account to default the value captured in the DFF for the account segment. Is this possible?

Version (include the version you are using, if applicable): 25A

Code Snippet (add any code snippets that support your topic, if applicable):