HR_COMPANY_COST_CENTERS not getting populated

Hi We are adding values from

Sysadmin-->Validation--->Values--->KFF and then we query the accounting flexfeild KFF.

We some new companies using this form but when we query those values in

HR_COMPANY_COST_CENTERS we are unable to find them.

Do we need to run some concurrent program before values defined in the above navigation are reflected in

HR_COMPANY_COST_CENTERS.

Thanks
Ashish