accounting setup for payables invoice

Hi all,
Under payables in one invoice when i go to view account , I am watching here one account is debit with some amount, but i could not
see where is this accounting method is fix. Its line type is "Charge" and no such account is not mention in distribution set, suppliers form, payables distribution set,
and this invoice is not match with any grn or po.

Kindly let me no which option is more to have such account set up?


Thanks