Paying Purchase Orders by Credit Card

Has anybody ever used a Supplier Relationship between a ‘Credit Card Supplier (Wells Fargo)’ and a ‘Supplier(Office Max)’ in order to pay the Credit Card Company who already paid the Supplier for the goods? AKA...Third Party Payments

Ex. We would setup Wells Fargo as a ‘Remit To Supplier’ on the Relationship tab for Office Max.  We would then cut a check to Wells Fargo for the Office Max invoice since Wells Fargo already paid Office Max.

If so, are there any known issues which you may have run intoregarding reporting or auditing?  Our client is wondering if anyone else uses this process to pay Credit Cards and if they have any issues in doing so.