Approval Assignment Question

 

We are on 11.5.10.2 

We are using Approval groups in our current position hierarchy for direct purchase requisitions which includes Account from 0 to Z. 

User requirement is now to add approval groups for indirect purchasing based on a certain accounts. 

Please suggest, if this will work if I add another line in the Approval group for the Purchase Requisition document with the applicable accounts?

Thanks 

JM