iExpenses GL account for expense items; can one item use two accounts?

My Client has a need for posting to multiple accounts based on user for one expense item. Example, User A chooses Expense Item 1 and the accounting goes to 610000; User B chooses Expense Item 1 and GL accounting goes to account 620000. Does R12.1.3 have this capability within the iExpenses setup or any other GL based rule?

thank you in advanced for any information provided.