Would like to set Approval Limit mix Item Code and Account Code

I have this informations
Item A01  has account code 115321 
Item A02  has account code 115321 

Approver1 has approval limit for Item A01  = 99,999,9999
Approver1 has approval limit for Account 115321  = 1,000,0000

Approver2 has unlimit for any Items and any Accounts.

Is it can be work if I set approval limit for Approver1 like this:
Item range       A01      99,999,9999
Account range  115321    1,000,0000

Can Approver1 finish approve PO item A01 without forward to Approver2?

If not, could anybody please suggest the way to fit my requirement?

Thank you so much.
Bim