Restrict certain combinations of Expense Templates

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What we want to do is restrict/ban combinations of certain expense template that users can choose.

For example we have an Expense Template for Overnights, Days, Over 8 hours and Under 4 hours away.

What I wanting to do is not allow someone to claim more than one of these within a 24 hour period eg not to be able to claim Day expense and an Over 8 Hours.

Think it could be done under ExpenseRuleSet workflow with a IF/THEN Statement.

Anyone done this?