Is there a way to put conditions on req header DFF value set value to have it be able to choose

Summary: We have a DFF on req header with list of values that procurement team adds one of these values to the req if applicable. We are wondering for one of the values on the value set tied to the DFF can we have a condition where if its a goods req then it will appear for someone to choose but for a services req it will be hidden and not available? Similiarily we are looking to do this for another value on the same value set values list if req is over 5k then its available but if not