Can we Create a Payment (PPR or associate Paygroup/Payment method) Based on DFF in Invoice header

Summary:

We have requirement like we have 2 different services under one business unit one is ACPNY other one is ACPSS. to differentiate the employee, they were used report establishment field and populated if the employee belongs to ACPNY or ACPSS.

So we are planning to create DFF at Expense report level and pass it to Invoice header now if we have to do payment do we have any option to differentiate ACPSS and ACPNY based on DFF?

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