Intercompany Clients created in AR to sync up with Sales Cloud

Summary: Hi Team, Is there any ESS job in place that needs to be run to get the data and sync it up for opportunity usage in Sales Cloud, primarily the lists that are created in AR and should be required to pull up to OSC along with the ideal Account object? We have both ERP and OSC capabilities being used, just needed to be sure if the process 'Synchronize Financials Accounts and Contacts with CX Cloud', if scheduled and successful, might resolve the issue. I was wondering though, though we have not run it as a requirement to do it, and looking forward to everyone's valuable input if they have any ideas or any alternates on it. Please let me know in the comments if the description is not clear enough.